Article

Photoelectron Spectrum and Electronic Structure of Triazadienyl Fluoride, N3F

  1. Paul Rademacher1,*,
  2. Andreas J. Bittner1,
  3. Gabriele Schatte2,
  4. Helge Willner2

Article first published online: 30 JAN 2006

DOI: 10.1002/cber.19881210325

Issue

Chemische Berichte

Chemische Berichte

Volume 121, Issue 3, pages 555–557, März 1988

Additional Information

How to Cite

Rademacher, P., Bittner, A. J., Schatte, G. and Willner, H. (1988), Photoelectron Spectrum and Electronic Structure of Triazadienyl Fluoride, N3F. Chem. Ber., 121: 555–557. doi: 10.1002/cber.19881210325

Author Information

  1. 1

    Institut für Organische Chemie der Universität-GHS Essen, Universitätsstraße 5–7, D-4300 Essen 1

  2. 2

    Institut für Anorganische Chemie der Universität Hannover, Callinstraße 9, D-3000 Hannover

*Institut für Organische Chemie der Universität-GHS Essen, Universitätsstraße 5–7, D-4300 Essen 1

Publication History

  1. Issue published online: 30 JAN 2006
  2. Article first published online: 30 JAN 2006
  3. Manuscript Received: 24 SEP 1987

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Abstract

The He(I) PE spectrum of the title compound 1 has been obtained. Based on quantum mechanical calculations, the ionization potentials have been assigned to molecular orbitals. Good correlation was obtained with the corresponding ionization potentials of chlorine azide (2), bromine azide (3), hydrazoic acid (4), and methyl azide (5). The low stability of 1 is apparent from its electronic structure.

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