Darstellung von [Dimethylamino(thiocarbonyl)thioamido]titan(IV)-dihalogeniden – Verbindungen mit kurzen Ti – N-Bindungen

Authors

  • Birgit Meller-Rehbein,

    1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400 Göttingen
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  • Herbert W. Roesky,

    Corresponding author
    1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400 Göttingen
    • Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400 Göttingen
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  • Mathias Noltemeyer

    1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400 Göttingen
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Abstract

Preparation of [Dimethylamino(thiocarbonyl)thioamido]titanium(IV) Dihalides – Compounds with Short Ti – N Bonds

Reaction of Me2NC(S)SN(SiMe3)2 (1) with TiCl4 and TiBr4 yields chemical structure image (2) and chemical structure image (3). Treatment of 2 and 3 with pyridine (py) leads to the solvates chemical structure image · 3 py [2a (X[DOUBLE BOND]Cl), 3a (X[DOUBLE BOND]Br)]. These adducts have been characterized by X-ray structure determination.

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