Neue Beiträge zur Chemie des Mangans: Synthese und Strukturen zweier monomerer MnII1-Verbindungen und eines hexanuklearen MnII/III1-Komplexes



New Contributions to the Chemistry of Manganese: Syntheses and Structures of two Monomeric MnII Compounds and a Hexanuclear MnII/III Complex

Two novel mononuclear manganese(II) complexes, Mn[OSi(OtBu)3]2·(Py)3 (2) and Mn[PhC6H4C(NSiMe3)2]2·THF (3), and a hexanuclear mixed-valence manganese(II/III) complex Mn6O2(O2CtBu)10·(Py)4 (5) have been prepared, and their structures have been determined by X-ray crystal structure analyses.