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Keywords:

  • biosynthesis;
  • enamide dealkylation;
  • nosiheptide;
  • post-translational modifications;
  • thiopeptides
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Serine qua non: Substitution of the extended Ser13 in the core peptide of nosiheptide by analogous amino acids prevented enamide dealkylation of the terminal residue for nosiheptide maturation.