Assess the C2-ation: A novel chlorinated perovskite-type oxide is prepared as catalyst for oxidative coupling of methane in a packed-bed reactor. Chlorine doping significantly improves the selectivity towards C2 species (C2H6 and C2H4). Furthermore, using N2O instead of O2 as oxidant, to some extent, prevented the deep oxidation of C2. As a result, a high C2 yield was acquired.
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