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Communication
Selective Debenzylation of Benzyl Protected Groups with SiliaCat Pd(0) under Mild Conditions
Article first published online: 21 APR 2011
DOI: 10.1002/cctc.201000420
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Pandarus, V., Béland, F., Ciriminna, R. and Pagliaro, M. (2011), Selective Debenzylation of Benzyl Protected Groups with SiliaCat Pd(0) under Mild Conditions. ChemCatChem, 3: 1146–1150. doi: 10.1002/cctc.201000420
Publication History
- Issue published online: 30 JUN 2011
- Article first published online: 21 APR 2011
- Manuscript Revised: 17 JAN 2011
- Manuscript Received: 25 NOV 2010
- Abstract
- Article
- References
- Cited By
Keywords:
- hydrogenolysis;
- debenzylation;
- nanoparticles;
- ormosil;
- palladium
A catalyst in the crowd: The selective debenzylation of aryl benzyl ethers, benzyl esters, and benzyl amines leaving other sensitive groups intact can be carried out in high yield under remarkably mild conditions [0.1 MPa (1 bar), H2 at room temperature] over a new series of recyclable palladium(0) heterogeneous catalysts.