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Allylic and Benzylic Oxidation over CrIII-Incorporated Mesoporous Zirconium Phosphate with 100 % Selectivity

Authors

  • Apurba Sinhamahapatra,

    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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  • Narottam Sutradhar,

    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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  • Sandip K. Pahari,

    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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  • Provas Pal,

    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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  • Dr. Hari C. Bajaj,

    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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  • Dr. Muthirulandi Jayachandran,

    1. Electrochemical Materials Science Division, Central Electrochemical Research Institute (CSIR), Karaikudi-630006, Tamilnadu (India)
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  • Dr. Asit Baran Panda

    Corresponding author
    1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
    • Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSIR), G.B. Marg, Bhavnagar-364021, Gujarat (India), Fax: (+91) 278-2567562
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Abstract

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Elite selection: The selective oxidation of allylic and benzylic compounds to the corresponding carbonyl compounds (enones), using H2O2 as oxidant and methanol as solvent over chromiumincorporated mesoporous zirconium phosphate, is evaluated.

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