Silver-Catalyzed Carbene Functionalization of Methane in Supercritical Carbon Dioxide

Authors

  • Prof. Dr. Michael P. Doyle

    Corresponding author
    1. Department of Chemistry and Biochemistry, 0107 Building-91, University of Maryland, College Park, MD 20742 (USA), Fax: (+11) 301-314-2779
    • Department of Chemistry and Biochemistry, 0107 Building-91, University of Maryland, College Park, MD 20742 (USA), Fax: (+11) 301-314-2779
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Abstract

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Supercritical, methane? It is insertion! Carbon–hydrogen insertion occurs between the least reactive hydrocarbon, methane, and the carbene intermediate formed from ethyl diazoacetate.

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