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Sterically Demanding Aryl Chlorides: No Longer a Problem for Borylations

  1. Christopher M. Vogels,
  2. Prof. Stephen A. Westcott*

Article first published online: 16 NOV 2011

DOI: 10.1002/cctc.201100249

Issue

ChemCatChem

ChemCatChem

Volume 4, Issue 1, pages 47–49, January 2, 2012

Additional Information

How to Cite

Vogels, C. M. and Westcott, S. A. (2012), Sterically Demanding Aryl Chlorides: No Longer a Problem for Borylations. ChemCatChem, 4: 47–49. doi: 10.1002/cctc.201100249

Author Information

  1. Department of Chemistry and Biochemistry, Mount Allison University, Sackville, NB E4L 1G8 (Canada), Fax: (+1) 506-364-2313

*Department of Chemistry and Biochemistry, Mount Allison University, Sackville, NB E4L 1G8 (Canada), Fax: (+1) 506-364-2313

Publication History

  1. Issue published online: 27 DEC 2011
  2. Article first published online: 16 NOV 2011
  3. Manuscript Received: 21 JUL 2011

Funded by

  • Natural Sciences and Engineering Research Council of Canada

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Keywords:

  • aryl chlorides;
  • boron;
  • borylation;
  • ligands;
  • phosphanes
Thumbnail image of graphical abstract

Borylation support group: Sterically demanding aryl chlorides can now be used effectively in the palladium-catalyzed borylation reaction. Phosphanes tethered to a silica support are used in the catalyst system to give aryl boronate esters in high yields.

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