1867-3899/asset/olbannerleft.gif?v=1&s=03d3513583332d2acd3b836ad464e0ef84187900)
1867-3899/asset/olbannercenter.gif?v=1&s=b9b3d9d069a1d1f534aa611bf32ecfa0a95f3203)
1867-3899/asset/olbannerright.gif?v=1&s=e35cf8a781685329bc4adde084aa82f981d9c4e7)
Communication
Recycling Chiral Copper Bis(oxazoline) Complexes in an Original Multireaction Procedure
Article first published online: 12 OCT 2011
DOI: 10.1002/cctc.201100250
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Didier, D. and Schulz, E. (2011), Recycling Chiral Copper Bis(oxazoline) Complexes in an Original Multireaction Procedure. ChemCatChem, 3: 1880–1884. doi: 10.1002/cctc.201100250
Publication History
- Issue published online: 8 DEC 2011
- Article first published online: 12 OCT 2011
- Manuscript Received: 22 JUL 2011
Funded by
- CNRS
- MESR
Keywords:
- asymmetric catalysis;
- cyclopropanation;
- ene reaction;
- N ligands;
- recycling
Precipitation–the solution? The recovery of a chiral copper(II) bis(oxazoline) catalyst by charge-transfer complexation and subsequent precipitation allows its efficient reuse in ene and cyclopropanation reactions for up to ten successive catalytic cycles and affords the desired products in high yields and enantioselectivities. The same catalyst batch is also successfully reused in three different asymmetric transformations in an original multireaction procedure.