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Communication
Selective Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM-5 Catalysts
Article first published online: 14 NOV 2011
DOI: 10.1002/cctc.201100273
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Zhao, C. and Lercher, J. A. (2012), Selective Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM-5 Catalysts. ChemCatChem, 4: 64–68. doi: 10.1002/cctc.201100273
Publication History
- Issue published online: 27 DEC 2011
- Article first published online: 14 NOV 2011
- Manuscript Revised: 10 OCT 2011
- Manuscript Received: 9 AUG 2011
Funded by
- European Graduate School for Sustainable Energy
Keywords:
- hydrodeoxygenation;
- lignin;
- palladium;
- supported catalysts;
- sustainable chemistry
Suffocating phenols: A catalyst system consisting of Pd/C and HZSM-5 shows an extremely high selectivity in removing oxygen-containing groups (hydroxyl, methoxy, ketone, alkyl![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
Oaryl, and arylOaryl) in lignin-derived substituted phenolic monomers and dimers through a metal-acid catalyzed cascade cleavage of CO bonds in phenolic dimers and the integrated hydrogenation and dehydration reactions in water at 473 K.