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Keywords:

  • C[BOND]H activation;
  • carbon dioxide fixation;
  • catalysis;
  • propiolic acids;
  • silver
Thumbnail image of graphical abstract

Terminally active: A reaction protocol that permits the C[BOND]H carboxylation of alkynes at low temperatures, with mild bases, at ambient CO2 pressure, in the presence of ppm-quantities of an inexpensive silver catalyst.