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C[BOND]H Carboxylation of Terminal Alkynes Catalyzed by Low Loadings of Silver(I)/DMSO at Ambient CO2 Pressure

Authors

  • Matthias Arndt,

    1. FB Chemie - Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921
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  • Eugen Risto,

    1. FB Chemie - Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921
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  • Thilo Krause,

    1. FB Chemie - Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921
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  • Prof. Dr. Lukas J. Gooßen

    Corresponding author
    1. FB Chemie - Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921
    • FB Chemie - Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921
    Search for more papers by this author

Abstract

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Terminally active: A reaction protocol that permits the C[BOND]H carboxylation of alkynes at low temperatures, with mild bases, at ambient CO2 pressure, in the presence of ppm-quantities of an inexpensive silver catalyst.

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