Communication

(Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber

  1. Youngjin Lee2,
  2. Dr. Yukihiro Motoyama1,*,
  3. Keita Tsuji2,
  4. Prof. Dr. Seong-Ho Yoon1,
  5. Prof. Dr. Isao Mochida1,
  6. Prof. Dr. Hideo Nagashima1

Article first published online: 18 APR 2012

DOI: 10.1002/cctc.201200058

Issue

ChemCatChem

ChemCatChem

Volume 4, Issue 6, pages 778–781, June 2012

Additional Information

How to Cite

Lee, Y., Motoyama, Y., Tsuji, K., Yoon, S.-H., Mochida, I. and Nagashima, H. (2012), (Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber. ChemCatChem, 4: 778–781. doi: 10.1002/cctc.201200058

Author Information

  1. 1

    Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan), Fax: (+81) 92-583-7839

  2. 2

    Graduate School of Engineering Sciences, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan)

*Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan), Fax: (+81) 92-583-7839

Publication History

  1. Issue published online: 25 MAY 2012
  2. Article first published online: 18 APR 2012
  3. Manuscript Received: 1 FEB 2012

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Keywords:

  • alkyne;
  • heterogeneous catalysis;
  • hydrogenation;
  • nitrogen-doped;
  • nanofiber;
  • palladium
Thumbnail image of graphical abstract

Doing things by half: Palladium nanoparticles supported on the nitrogen-doped carbon nanofiber (Pd/N-CNF-H) are synthesized by thermally decomposing Pd2(dba)3⋅CHCl3 in toluene in the presence of N-CNF-H, and act as efficient catalysts for the partial hydrogenation of internal alkynes to the corresponding (Z)-alkenes in high turnover numbers.

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