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(Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber

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Doing things by half: Palladium nanoparticles supported on the nitrogen-doped carbon nanofiber (Pd/N-CNF-H) are synthesized by thermally decomposing Pd2(dba)3⋅CHCl3 in toluene in the presence of N-CNF-H, and act as efficient catalysts for the partial hydrogenation of internal alkynes to the corresponding (Z)-alkenes in high turnover numbers.

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