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Magnetic Fe–Ni Alloy Catalyzed Suzuki Cross-Coupling Reactions of Aryl Halides with Phenylboronic Acid

Authors

  • Dr. Rongzhao Zhang,

    1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088
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  • Dr. Chengxia Miao,

    1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088
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  • Shoufeng Wang,

    1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088
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  • Prof. Dr. Chungu Xia,

    1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088
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  • Prof. Dr. Wei Sun

    Corresponding author
    1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088
    2. Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123 (China)
    • State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China), Fax: (+86) 931-827-7088

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Abstract

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Alloy there matey! The inexpensive and readily prepared magnetic Fe–Ni alloy is employed in the Suzuki reactions of aryl halides with phenylboronic acid. The products are obtained in moderate to excellent yields in the absence of a reducing agent. The magnetic nature of the catalyst is beneficial for the separation of the products, but the recyclability of the catalyst is poor, probably as a result of oxidation and leaching.

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