Communication

Supramolecular Ligands in Gold(I) Catalysis

  1. Dr. Rafael Gramage-Doria,
  2. Rosalba Bellini,
  3. Jeroen Rintjema,
  4. Prof. Dr. Joost N. H. Reek*

Article first published online: 25 OCT 2012

DOI: 10.1002/cctc.201200541

Issue

ChemCatChem

ChemCatChem

Special Issue: Homogeneous Catalysis

Volume 5, Issue 5, pages 1084–1087, May 2013

Additional Information

How to Cite

Gramage-Doria, R., Bellini, R., Rintjema, J. and Reek, J. N. H. (2013), Supramolecular Ligands in Gold(I) Catalysis. ChemCatChem, 5: 1084–1087. doi: 10.1002/cctc.201200541

Author Information

  1. Supramolecular and Homogeneous Catalysis van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 20-525-5604 http://www.science.uva.nl/research/imc/HomKat/

*Supramolecular and Homogeneous Catalysis van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 20-525-5604 http://www.science.uva.nl/research/imc/HomKat/

Publication History

  1. Issue published online: 26 APR 2013
  2. Article first published online: 25 OCT 2012
  3. Manuscript Received: 8 AUG 2012

Funded by

  • University of Amsterdam
  • The Netherlands Organization for Scientific Research-Chemical Sciences
  • National Research School for Catalysis

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Keywords:

  • allenes;
  • gold;
  • phosphoramidites;
  • regioselectivity;
  • supramolecular chemistry
Thumbnail image of graphical abstract

Golden (I): A supramolecular ligand–template strategy is applied to gold(I) catalysis. The supramolecular ligands, formed from a phosphoramidite backbone and two templates, display different regioselectivity in the hydroalkoxylation of allenes compared to non-supramolecular analogues. Based on these findings, the catalytic activity of gold(I) complexes could be tunable at a supramolecular level.

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