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Keywords:

  • gold;
  • heterogeneous catalysis;
  • ligand effects;
  • metal–organic frameworks;
  • polymers
Thumbnail image of graphical abstract

The best things in life are free: LSK-1 is a porous polymer with free phosphine sites homogeneously distributed within the structure. Post- functionalization gave a AuI-impregnated solid (16 % w/w) that was used as a recyclable heterogeneous catalyst.