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AuI Catalysis on a Coordination Polymer: A Solid Porous Ligand with Free Phosphine Sites

Authors

  • Jiří Václavík,

    1. Department of Chemistry and Applied Biosciences, Laboratory of Chemical and Bioengineering, ETH Zurich, CH-8093, Zürich (Switzerland)
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  • Marco Servalli,

    1. Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
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  • Dr. Christian Lothschütz,

    1. Department of Chemistry and Applied Biosciences, Laboratory of Chemical and Bioengineering, ETH Zurich, CH-8093, Zürich (Switzerland)
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  • Dr. Jakub Szlachetko,

    1. Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
    2. Institute of Physics, University of Kielce, 25-314 Kielce (Poland)
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  • Dr. Marco Ranocchiari,

    Corresponding author
    1. Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
    • Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
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  • Prof. Jeroen A. van Bokhoven

    Corresponding author
    1. Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
    2. Department of Chemistry and Applied Biosciences, Laboratory of Chemical and Bioengineering, ETH Zurich, CH-8093, Zürich (Switzerland)
    • Laboratory of Catalysis and Sustainable Chemistry, Paul Scherrer Institute, CH-5232, Villigen PSI (Switzerland)
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Abstract

original image

The best things in life are free: LSK-1 is a porous polymer with free phosphine sites homogeneously distributed within the structure. Post- functionalization gave a AuI-impregnated solid (16 % w/w) that was used as a recyclable heterogeneous catalyst.

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