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Keywords:

  • copper;
  • cross-coupling;
  • reaction mechanisms;
  • rearrangement;
  • structure elucidation
Thumbnail image of graphical abstract

The Hurtley locker: The first examples of copper-catalyzed Cmath image[BOND]Cmath image cross-coupling with the direct involvement of a CuI/CuIII catalytic cycle are reported. The product rapidly reorganizes into a 1,2-dihydroisoquinoline scaffold.