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Catalytic Bio-Supramolecular Photochirogenesis: Batch-Operated Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate with Human Serum Albumin

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Abstract

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Chiral induction: Catalytic bio-supramolecular photochirogenesis is achieved for the enantiodifferentiating [4+4] photocyclodimerization of 2-anthracenecarboxylate by repeatedly using human serum albumin (HSA) as a chiral mediator; the original high enantiomeric excess values (up to 80–90 %) are preserved.

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