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Direct Synthesis of Amides from Carboxylic Acids and Amines by Using Heterogeneous Catalysts: Evidence of Surface Carboxylates as Activated Electrophilic Species

Authors

  • Dr. Chiara Deiana,

    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
    2. Interdepartmental Centre of Excellence, “Nanostructured Interfaces and Surfaces-NIS”, University of Torino, Via P. Giuria 7, 10125 Torino (Italy)
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    • These authors contributed equally to this work.

  • Dr. Yuriy Sakhno,

    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
    2. Interdepartmental Centre of Excellence, “Nanostructured Interfaces and Surfaces-NIS”, University of Torino, Via P. Giuria 7, 10125 Torino (Italy)
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    • These authors contributed equally to this work.

  • Marco Fabbiani,

    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
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  • Dr. Marco Pazzi,

    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
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  • Prof. Marco Vincenti,

    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
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  • Prof. Gianmario Martra

    Corresponding author
    1. Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
    2. Interdepartmental Centre of Excellence, “Nanostructured Interfaces and Surfaces-NIS”, University of Torino, Via P. Giuria 7, 10125 Torino (Italy)
    • Department of Chemistry, University of Torino, Via P. Giuria 7, 10125 Torino (Italy), Fax: (+39) 0116707855
    Search for more papers by this author

Abstract

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Amide synthesis: In situ IR spectroscopy and HRMS provided evidence of the activation of surface carboxylates at mild temperatures (about 323 K) for the direct synthesis of amides from carboxylic acids and amines.

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