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Keywords:

  • allylic compounds;
  • heterogeneous catalysis;
  • isomerization;
  • supported catalysts;
  • vanadium
Thumbnail image of graphical abstract

Promotion by group high five: Silica-supported monomeric vanadium-oxide promoted the isomerization of various allylic alcohols, including under scaled-up and solvent-free reaction conditions. This catalyst also exhibited high reusability with no drop in activity.