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Simple and Efficient 1,3-Isomerization of Allylic Alcohols using a Supported Monomeric Vanadium-Oxide Catalyst

Authors

  • Dr. Takato Mitsudome,

    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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  • Shoichiro Sueoka,

    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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  • Satoshi Ikeda,

    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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  • Dr. Tomoo Mizugaki,

    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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  • Prof. Dr. Koichiro Jitsukawa,

    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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  • Prof. Dr. Kiyotomi Kaneda

    Corresponding author
    1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
    2. Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)
    • Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260
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Abstract

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Promotion by group high five: Silica-supported monomeric vanadium-oxide promoted the isomerization of various allylic alcohols, including under scaled-up and solvent-free reaction conditions. This catalyst also exhibited high reusability with no drop in activity.

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