Direct C sp2[BOND]H and C sp3[BOND]H Arylation Enabled by Heterogeneous Palladium Catalysts

Authors

  • Dr. Laurent Djakovitch,

    1. Université de Lyon, CNRS, UMR 5256, IRCELYON, Institut de recherches sur la catalyse et l'environnement de Lyon, 2 avenue Albert Einstein, F-69626 Villeurbanne (France)
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  • Prof. Dr. François-Xavier Felpin

    Corresponding author
    1. Université de Nantes, UFR des Sciences et des Techniques, CNRS UMR 6230, CEISAM, 2 rue de la Houssinière, 44322 Nantes Cedex 3 (France), Fax: (+33) 251-125-402
    2. Institut Universitaire de France, 103 blvd St Michel, 75005 Paris Cedex 5 (France)
    • Université de Nantes, UFR des Sciences et des Techniques, CNRS UMR 6230, CEISAM, 2 rue de la Houssinière, 44322 Nantes Cedex 3 (France), Fax: (+33) 251-125-402

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Abstract

This review gives an overview of direct C[BOND]H arylation catalyzed by heterogeneous Pd catalysts. The efficiency of the different forms of heterogeneous Pd catalysts is discussed with a critical view of the transformations attainable. If experimental evidence is provided, mechanistic considerations on the true nature of the catalysis, that is, heterogeneous versus homogeneous, are discussed as well.

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