Simultaneous Production of Biodiesel and Free Lutein from Chlorella vulgaris

Authors

  • C. Prommuak,

    1. Chemical Engineering Research Unit for Value Adding of Bioresources, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok, Thailand
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  • P. Pavasant,

    1. Chemical Engineering Research Unit for Value Adding of Bioresources, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok, Thailand
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  • A. T. Quitain,

    1. Graduate School of Science and Technology, Kumamoto University, Kumamoto, Japan
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  • M. Goto,

    1. Department of Chemical Engineering, Graduate School of Engineering, Nagoya University, Nagoya, Japan
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  • A. Shotipruk

    Corresponding author
    1. Chemical Engineering Research Unit for Value Adding of Bioresources, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok, Thailand
    • Chemical Engineering Research Unit for Value Adding of Bioresources, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok, Thailand
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Abstract

Biodiesel and valuable free lutein were demonstrated to be simultaneously produced from Chlorella vulgaris lipid extracts. The alkali catalyst used in the transesterification of triglycerides acted as a reactant in converting lutein fatty acid esters to free lutein. A maximum biodiesel yield of 33.6 % by weight of the algal lipids was obtained after a 4-h reaction with MeOH at the MeOH/biomass ratio of 16:1 using 6 % alkali catalyst. The excess of alkali and MeOH employed in the production of biodiesel ensured the complete saponification of all lutein fatty acid esters to free lutein, giving a maximum yield of 2.3 % by weight of the algal lipids. In addition, a process for the separation of the biodiesel and free lutein products from the reaction mixture is proposed. Finally, a preliminary economic assessment was conducted, the results of which suggest that the process for the simultaneous production of biodiesel and lutein from C. vulgaris may be economically feasible.

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