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Development of Palladium–Carbene Catalysts for Telomerization and Dimerization of 1,3-Dienes: From Basic Research to Industrial Applications

  1. Nicolas D. Clement Dr.,
  2. Lucie Routaboul Dr.,
  3. Anne Grotevendt,
  4. Ralf Jackstell Dr.,
  5. Matthias Beller Prof.

Article first published online: 4 AUG 2008

DOI: 10.1002/chem.200800858

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 14, Issue 25, pages 7408–7420, August 28, 2008

Additional Information

How to Cite

Clement, Nicolas D., Routaboul, L., Grotevendt, A., Jackstell, R. and Beller, M. (2008), Development of Palladium–Carbene Catalysts for Telomerization and Dimerization of 1,3-Dienes: From Basic Research to Industrial Applications. Chem. Eur. J., 14: 7408–7420. doi: 10.1002/chem.200800858

Author Information

  1. Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000

Publication History

  1. Issue published online: 25 AUG 2008
  2. Article first published online: 4 AUG 2008

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Keywords:

  • dimerization;
  • green chemistry;
  • N-heterocyclic carbenes;
  • palladium;
  • telomerization

Abstract

The following account summarises recent developments in the area of palladium-catalysed telomerisation and dimerisation reactions of 1,3-dienes. The most active types of catalyst, palladium–carbene complexes, were tested in pilot plant and proved to be industrially viable.

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