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Keywords:

  • chirality;
  • helical structures;
  • structure elucidation;
  • supramolecular chemistry;
  • X-ray diffraction

Graphical Abstract

Thumbnail image of graphical abstract

Foldamers at an angle: Metal-directed assembly dictates the perpendicular or parallel orientation of helically folded aromatic oligoamide modules and mediates the communication of their relative handedness (see figure).