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Concept
Artificial Enzyme Catalysis Controlled and Driven by Light
Article first published online: 16 OCT 2008
DOI: 10.1002/chem.200801179
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Knör, G. (2009), Artificial Enzyme Catalysis Controlled and Driven by Light. Chemistry - A European Journal, 15: 568–578. doi: 10.1002/chem.200801179
Publication History
- Issue published online: 29 DEC 2008
- Article first published online: 16 OCT 2008
Funded by
- DFG
- Abstract
- Article
- References
- Cited By
Keywords:
- artificial photosynthesis;
- bioinorganic chemistry;
- coordination chemistry;
- enzyme catalysis;
- photochemistry
Graphical Abstract
Bio-inspired chemistry! Photochemical key steps (see figure) provide a versatile tool for the remote control of chemical and biological processes. Many challenging reactions, which otherwise could hardly be achieved at all, are readily triggered and powered by photons. This Concept article explores the design principles and potential applications of biomimetic catalysis based on photoresponsive molecular systems.
Abstract
Bio-inspired chemistry based on photoresponsive molecules is a rapidly developing new strategy to mimic the function of various biological systems. The interaction of electromagnetic radiation with molecular systems is ideally suited for the control and powering of dynamic processes at the speed of light. Besides typical applications in artificial photosynthesis, many other aspects, such as the catalytic turnover of substrates or the controlled release or uptake of small bioactive molecules, are readily verified with light-driven model systems. The potential of this novel approach in biomimetic chemistry is briefly explored in this concept article.