Communication

Metal-Tuned Photochemistry of Metallocene-Substituted Chromium(0)–Carbene Complexes

  1. Marta L. Lage,
  2. Israel Fernández Dr.,
  3. María J. Mancheño Prof.,
  4. Mar Gómez-Gallego Prof.,
  5. Miguel A. Sierra Prof.

Article first published online: 3 DEC 2008

DOI: 10.1002/chem.200802005

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 15, Issue 3, pages 593–596, January 5, 2009

Additional Information

How to Cite

Lage, Marta L., Fernández, I., Mancheño, María J., Gómez-Gallego, M. and Sierra, Miguel A. (2009), Metal-Tuned Photochemistry of Metallocene-Substituted Chromium(0)–Carbene Complexes. Chem. Eur. J., 15: 593–596. doi: 10.1002/chem.200802005

Author Information

  1. Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040 Madrid (Spain), Fax: (+34) 913944310

Publication History

  1. Issue published online: 29 DEC 2008
  2. Article first published online: 3 DEC 2008
  3. Manuscript Received: 22 OCT 2008

Funded by

  • MEC. Grant Number: CTQ2007-67730-C02–01
  • Consolider-Ingenio 2010. Grant Numbers: CSD2007-0006, CCG07-UCM2596

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Keywords:

  • carbene ligands;
  • density functional calculations;
  • lactams;
  • metallocenes;
  • photochemistry
Thumbnail image of graphical abstract

Ferrocene or ruthenocene? Computational (DFT) methods predicted a metal-dependent photochemistry for metallocenyl–chromium(0)–carbene complexes (see scheme). These theoretical predictions are fully confirmed by the experimental results.

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