1521-3765/asset/2111_left.gif?v=1&s=0561086440e3dfc935e925fa17e4b4c8a50bbfe3)
1521-3765/asset/2111_right.gif?v=1&s=9fa3626b72da80da2a89f547de4d2cc5d7fadfe6)
Communication
The First Flights of a Molecular Shuttle Transporting Elements: Easy One-pot Formation of Organic Cyclic Arsanes, Stibanes and Bismutanes
Article first published online: 4 DEC 2008
DOI: 10.1002/chem.200802007
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Baccolini, G., Boga, C., Mazzacurati, M. and Micheletti, G. (2009), The First Flights of a Molecular Shuttle Transporting Elements: Easy One-pot Formation of Organic Cyclic Arsanes, Stibanes and Bismutanes. Chem. Eur. J., 15: 597–599. doi: 10.1002/chem.200802007
Publication History
- Issue published online: 29 DEC 2008
- Article first published online: 4 DEC 2008
- Manuscript Received: 31 OCT 2008
Funded by
- Alma Mater Studiorum—Università di Bologna. Grant Number: RFO funds
- MIUR. Grant Number: PRIN Project 2007
Keywords:
- antimony;
- arsenic;
- bismuth;
- phosphorus heterocycles;
- pnictides
Maiden voyage: New arsenic-, antimony- and bismuth-donor reagents (1 b–d) are used in a one-pot synthesis of cyclic arsanes, stibanes and bismutanes through a procedure in which the simultaneous formation of three C![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
As, CSb or CBi bonds is achieved. At the end of the reaction, the element-donor reagent can be easily re-formed “in situ” and recycled, as in a catalytic process.