FeNCN and Fe(NCNH)2: Synthesis, Structure, and Magnetic Properties of a Nitrogen-Based Pseudo-oxide and -hydroxide of Divalent Iron

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Abstract

Iron man challenge: Iron carbodiimide, FeNCN, and its precursor iron (bis)monohydrocyanamide, Fe(NCNH)2, have been synthesized and physically characterized. Both FeNCN and Fe(NCNH)2 exhibit nitrogen-mediated antiferromagnetic superexchange interactions with reduced magnetic moments very similar, but not identical, to the correlated 3d oxides.

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