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Chemo- and Regioselective Palladium-Catalyzed Oxycyclization Reactions of Allendiols: Preparation of Five-, Six-, and Eight-Membered Cycles



Positive discrimination: Chemo- and regioselective palladium-catalyzed cycloetherification of allendiols, namely β,γ- and γ,δ-allendiols, may occur by judicious choice of palladium-catalyzed conditions owing to their potential ability to discriminate between both nucleophilic sites (see scheme).

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