Control of the Supramolecular Excimer Formation of Thioflavin T within a Cucurbit[8]uril Host: A Fluorescence On/Off Mechanism

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Abstract

On or off? A new excimer band at λ=570 nm was visualized during the noncovalent host–guest interaction between thioflavin T (ThT) and cucurbit[8]uril (CB8). Controlled dissociation of this assembly in the presence of Ca2+ was demonstrated as an on/off fluorescence switch (see picture).

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