Communication

Crown-Ether-Like PbII-Metal Framework with Dual- and Bimodal Emissive Properties Based on Its Photochromic Precursor by Leaching

  1. You-Yun Jiang,
  2. Shu-Kui Ren,
  3. Jian-Ping Ma,
  4. Qi-Kui Liu,
  5. Yu-Bin Dong Prof. Dr.

Article first published online: 10 SEP 2009

DOI: 10.1002/chem.200901412

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 15, Issue 41, pages 10742–10746, October 19, 2009

Additional Information

How to Cite

Jiang, Y.-Y., Ren, S.-K., Ma, J.-P., Liu, Q.-K. and Dong, Y.-B. (2009), Crown-Ether-Like PbII-Metal Framework with Dual- and Bimodal Emissive Properties Based on Its Photochromic Precursor by Leaching. Chemistry - A European Journal, 15: 10742–10746. doi: 10.1002/chem.200901412

Author Information

  1. College of Chemistry, Chemical Engineering and Materials Science, Key Lab of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Normal University, Jinan, 250014 (P. R. China), Fax: (+86) 531-82615258

Publication History

  1. Issue published online: 13 OCT 2009
  2. Article first published online: 10 SEP 2009
  3. Manuscript Received: 26 MAY 2009

Funded by

  • NSFC. Grant Numbers: 20871076, 20671060
  • Shangdong Natural Science Foundation. Grant Number: JQ200803
  • Ministry of Education. Grant Number: 200804450001

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Keywords:

  • lanthanides;
  • leaching;
  • lead;
  • metal–organic frameworks;
  • photochromism

Graphical Abstract

Thumbnail image of graphical abstract

Kingdom for a lead crown: A crown-ether-like, open PbII framework is generated from its phtotochromic precursor by a leaching approach. The dual and bimodal emissions are successfully realized by intercalation of the different Ln3+ hydrates into the hollow PbII framework based on a guest-driven approach (see graphic).

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