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Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

  1. Tomohiko Inagaki,
  2. Le Thanh Phong,
  3. Akihiro Furuta,
  4. Jun-ichi Ito Assist. Prof. Dr.,
  5. Hisao Nishiyama Prof. Dr.

Article first published online: 29 JAN 2010

DOI: 10.1002/chem.200903118

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 16, Issue 10, pages 3090–3096, March 8, 2010

Additional Information

How to Cite

Inagaki, T., Phong, L., Furuta, A., Ito, J.-i. and Nishiyama, H. (2010), Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands. Chem. Eur. J., 16: 3090–3096. doi: 10.1002/chem.200903118

Author Information

  1. Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464–8603 (Japan), Fax: (+81) 52-789-3209

Publication History

  1. Issue published online: 1 MAR 2010
  2. Article first published online: 29 JAN 2010
  3. Manuscript Received: 13 NOV 2009

Funded by

  • Ministry of Education, Culture, Sports, Science and Technology of Japan. Grant Number: 460:18065011
  • Japan Society for the Promotion of Science. Grant Number: 18350049

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Keywords:

  • asymmetric catalysis;
  • bisoxazoline ligands;
  • cobalt;
  • hydrosilylation;
  • iron

Abstract

Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.

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