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Communication
Metal Dependence of Network Dimensionality in 1,2,4-Diazaphospholide Coordination Polymers
Article first published online: 9 FEB 2010
DOI: 10.1002/chem.200903184
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Schramm, P., Leineweber, A., Lissner, F. and Gudat, D. (2010), Metal Dependence of Network Dimensionality in 1,2,4-Diazaphospholide Coordination Polymers. Chem. Eur. J., 16: 2982–2985. doi: 10.1002/chem.200903184
Publication History
- Issue published online: 1 MAR 2010
- Article first published online: 9 FEB 2010
- Manuscript Received: 19 NOV 2009
Keywords:
- coordination polymers;
- heterophospholes;
- N ligands;
- P ligands
The right to choose: 1,2,4-Diazaphospholide anions support the predictable construction of coordination polymer networks of different topology by switching between bidentate (κN,κN′) and tridentate (κN,κN′,κP) coordination depending on the choice of the metal (see picture); furthermore, the ligand exhibits a remarkable difference to 1,2,4-triazolides because the diffuse lone pair at phosphorus permits μ2(P)-bridging coordination.