Get access

Polar 2D Sheet versus Nonpolar 1D Helix Metallosupramolecular Architectures Based on M6M′8 (M=PdII, NiII; M′=CuI, AgI) Cage Clusters with D-Penicillaminate

Authors

  • Dr. Nobuto Yoshinari,

    1. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan), Fax: (+81) 6-6850-5765
    Search for more papers by this author
  • Dr. Asako Igashira-Kamiyama,

    1. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan), Fax: (+81) 6-6850-5765
    Search for more papers by this author
  • Prof. Takumi Konno

    Corresponding author
    1. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan), Fax: (+81) 6-6850-5765
    • Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan), Fax: (+81) 6-6850-5765
    Search for more papers by this author

Abstract

original image

To coil or not to coil: Chiral S-bridged 14-nuclear clusters with 12 free carboxylate groups, [M6M′8(D-pen)12Cl]5− (M=PdII, NiII; M′=CuI, AgI; D-pen=D-penicillaminate; see scheme), prepared from [M(D-pen)2]2− and M′Cl, were organized into heterotrimetallic supramolecular structures in combination with La3+.

Get access to the full text of this article

Ancillary