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A General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Triflates

Authors

  • Xiao-Feng Wu,

    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Basker Sundararaju,

    1. Catalyse et Organométalliques, Institut Sciences Chimiques de Rennes, UMR 6226-CNRS-Université de Rennes, Av. Général Leclerc, 35042 Rennes (France)
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  • Dr. Helfried Neumann,

    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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  • Prof. Dr. Pierre H. Dixneuf,

    1. Catalyse et Organométalliques, Institut Sciences Chimiques de Rennes, UMR 6226-CNRS-Université de Rennes, Av. Général Leclerc, 35042 Rennes (France)
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  • Prof. Dr. Matthias Beller

    Corresponding author
    1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
    • Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-5000
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Abstract

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Trifling with triflates: A new protocol for the carbonylative Sonogashira reactions of aryl triflates (see scheme) that provides a significant extension of this interesting methodology is described.

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