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Syntheses and X-ray Crystal Structures of Organoantimony Diazides

Authors

  • Benjamin Lyhs,

    1. Institute of Inorganic Chemistry, University of Duisburg-Essen, S07S03C30, 45117 Essen (Germany), Fax: (+49) 201-1833830
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  • Dieter Bläser,

    1. Institute of Inorganic Chemistry, University of Duisburg-Essen, S07S03C30, 45117 Essen (Germany), Fax: (+49) 201-1833830
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  • Dr. Christoph Wölper,

    1. Institute of Inorganic Chemistry, University of Duisburg-Essen, S07S03C30, 45117 Essen (Germany), Fax: (+49) 201-1833830
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  • Prof. Dr. Stephan Schulz

    Corresponding author
    1. Institute of Inorganic Chemistry, University of Duisburg-Essen, S07S03C30, 45117 Essen (Germany), Fax: (+49) 201-1833830
    • Institute of Inorganic Chemistry, University of Duisburg-Essen, S07S03C30, 45117 Essen (Germany), Fax: (+49) 201-1833830
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Abstract

Antimony(III) complexes of the general type LSbF2 (3: L1=[tBuC(NiPr)2]; 4: L2=[tBuC(NDipp)2], Dipp=2,6-iPr2C6H3) and LSb(N3)2 (6: L1; 7: L2) were prepared in high yields and characterized by elemental analyses, NMR and IR spectroscopy and single-crystal X-ray diffraction. Moreover, the solid-state structures of [L2SbF2][L2Li] (5), [L2AlH2] (1), and [L′H][L′K(thf)3] (2; L′=HC(NDipp)2) are described, in which the Li (5) and K atoms (2) adopt rather unusual coordination modes.

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