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Radical Carbonitrosation and Recycling of the Waste Gas Nitrogen Monoxide

Authors

  • Cristina de Salas,

    1. Department für Chemie und Pharmazie, Pharmazeutische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Schuhstrasse 19, 91052 Erlangen (Germany), Fax: (+49) 9131-852-2585
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  • Dr. Olga Blank,

    1. Fakultät für Chemie und Biochemie, Organische Chemie 1, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching bei München (Germany)
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  • Prof. Dr. Markus R. Heinrich

    Corresponding author
    1. Department für Chemie und Pharmazie, Pharmazeutische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Schuhstrasse 19, 91052 Erlangen (Germany), Fax: (+49) 9131-852-2585
    • Department für Chemie und Pharmazie, Pharmazeutische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Schuhstrasse 19, 91052 Erlangen (Germany), Fax: (+49) 9131-852-2585
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Abstract

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NO recycling! A new type of Meerwein arylation has been developed by using the most simple nitrogen-centered radical scavenger, nitrogen monoxide, and arenediazonium salts in the presence or absence of iron(II) sulfate. Owing to its low sensitivity towards oxygen, the reaction allows the recycling of nitrogen monoxide produced as waste gas.

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