Communication

An Approach to the Regioselective Diamination of Conjugated Di- and Trienes

  1. Anton Lishchynskyi1,
  2. Prof. Dr. Kilian Muñiz1,2,*

Article first published online: 25 JAN 2012

DOI: 10.1002/chem.201103435

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 18, Issue 8, pages 2212–2216, February 20, 2012

Additional Information

How to Cite

Lishchynskyi, A. and Muñiz, K. (2012), An Approach to the Regioselective Diamination of Conjugated Di- and Trienes. Chem. Eur. J., 18: 2212–2216. doi: 10.1002/chem.201103435

Author Information

  1. 1

    Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona (Spain), Fax: (+34) 977-920-224

  2. 2

    Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, 08010 Barcelona (Spain)

*Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona (Spain), Fax: (+34) 977-920-224

Publication History

  1. Issue published online: 10 FEB 2012
  2. Article first published online: 25 JAN 2012
  3. Manuscript Revised: 18 DEC 2011
  4. Manuscript Received: 1 NOV 2011

Funded by

  • Fundación ICIQ
  • Consolider INTECAT 2010. Grant Number: CSD2006–0003
  • Fonds der Chemischen Industrie
  • the French MESR

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Keywords:

  • amines;
  • amination;
  • butadienes;
  • diamination;
  • iodine;
  • oxidation
Thumbnail image of graphical abstract

It's do or diaminate: The selective diamination of 1,3-butadienes in the presence of hypervalent iodine reagents has been developed. This oxidation process proceeds with complete selectivity in favor of diamination. Depending on the substrate, it proceeds either with 1,2- or 1,4-regioselectivity (see scheme).

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