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Keywords:

  • hydrogen bonding;
  • kinetics;
  • proton transfer;
  • proton-coupled electron transfer
Thumbnail image of graphical abstract

Life of triad: The lifetime of a charge-separated state (see figure) increases from about 50 to 2000 ns when the solvent is changed from aprotic CH2Cl2 to the strong hydrogen-bond donor hexafluoroisopropanol.