Sequestering Aromatic Molecules with a Spin-Crossover FeII Microporous Coordination Polymer

Authors

  • Francisco J. Muñoz-Lara,

    1. Institut de Ciència Molecular/Departament de Química Inorgánica, Universitat de València, Edifici d'Instituts de Paterna, Carrer Catedràtic José Beltrán Martínez 2, 46980 Paterna, València (Spain)
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  • Dr. Ana B. Gaspar,

    1. Institut de Ciència Molecular/Departament de Química Inorgánica, Universitat de València, Edifici d'Instituts de Paterna, Carrer Catedràtic José Beltrán Martínez 2, 46980 Paterna, València (Spain)
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  • Prof. Dr. M. Carmen Muñoz,

    1. Departament de Física Aplicada, Universitat Politècnica de València, Camí de Vera s/n, 46022 València (Spain)
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  • Masashi Arai,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Prof. Dr. Susumu Kitagawa,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Prof. Dr. Masaaki Ohba,

    1. Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581 (Japan)
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  • Prof. Dr. José Antonio Real

    Corresponding author
    1. Institut de Ciència Molecular/Departament de Química Inorgánica, Universitat de València, Edifici d'Instituts de Paterna, Carrer Catedràtic José Beltrán Martínez 2, 46980 Paterna, València (Spain)
    • Institut de Ciència Molecular/Departament de Química Inorgánica, Universitat de València, Edifici d'Instituts de Paterna, Carrer Catedràtic José Beltrán Martínez 2, 46980 Paterna, València (Spain)
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Abstract

original image

All in a spin: A series of three-dimensional porous coordination polymer {Fe(dpe)[Pt(CN)4]}⋅G (dpe=1,2-di(4-pyridyl)ethylene; G=phenazine, anthracene, or naphthalene) exhibiting spin crossover and host–guest functions is reported. The magnetic properties of the framework are very sensitive to the chemical nature (aromatic or hydroxilic solvents) and the size of the included guest molecules.

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