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Controlling State of Breathing of Two Isoreticular Microporous Metal–Organic Frameworks with Triazole Homologues

Authors

  • Zhi-Qiang Jiang,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (P.R. China)
    2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249 Beijing, (P.R. China)
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    • These authors contributed equally to this work.

  • Gui-Yuan Jiang,

    1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249 Beijing, (P.R. China)
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    • These authors contributed equally to this work.

  • Dr. Fei Wang,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (P.R. China)
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  • Prof. Zhen Zhao,

    1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249 Beijing, (P.R. China)
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  • Prof. Dr. Jian Zhang

    Corresponding author
    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (P.R. China)
    • State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (P.R. China)
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Abstract

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Breathing effect: Using two triazole homologues (1H-benzotriazole and 1,2,3-1H-triazole), two isoreticular microporous Zn–benzenedicarboxylate frameworks 1 and 2 with reverse dynamic features are presented, in which different sized triazole ligands effectively control the state of breathing of two flexible frameworks (see figure).

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