Communication

“Bottom-Up” Embedding of the Jørgensen–Hayashi Catalyst into a Chiral Porous Polymer for Highly Efficient Heterogeneous Asymmetric Organocatalysis

  1. Chang An Wang,
  2. Zhi Kun Zhang,
  3. Tao Yue,
  4. Ya Lei Sun,
  5. Lei Wang,
  6. Wei David Wang,
  7. Dr. Yuan Zhang,
  8. Chong Liu,
  9. Prof. Dr. Wei Wang*

Article first published online: 4 MAY 2012

DOI: 10.1002/chem.201200753

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 18, Issue 22, pages 6718–6723, May 29, 2012

Additional Information

How to Cite

Wang, C. A., Zhang, Z. K., Yue, T., Sun, Y. L., Wang, L., Wang, W. D., Zhang, Y., Liu, C. and Wang, W. (2012), “Bottom-Up” Embedding of the Jørgensen–Hayashi Catalyst into a Chiral Porous Polymer for Highly Efficient Heterogeneous Asymmetric Organocatalysis. Chem. Eur. J., 18: 6718–6723. doi: 10.1002/chem.201200753

Author Information

  1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557

*State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557

Publication History

  1. Issue published online: 23 MAY 2012
  2. Article first published online: 4 MAY 2012
  3. Manuscript Received: 6 MAR 2012

Funded by

  • National Natural Science Foundation of China. Grant Number: 21172103
  • Chinese Ministry of Education. Grant Number: 309028

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Keywords:

  • asymmetric catalysis;
  • heterogeneous catalysis;
  • organocatalysis;
  • Michael addition;
  • supported catalysts
Thumbnail image of graphical abstract

The only way is up! “Bottom-up” construction of a robust chiral porous polymer (JH-CPP) embedded with the Jørgensen–Hayashi catalyst (JH) has been successfully achieved for highly efficient heterogeneous organocatalysis. The high BET surface area, wide openings and interconnected nanopores of JH-CPP increase the accessibility of catalytic sites and as such the catalyst shows excellent activity in catalyzing the asymmetric Michael addition reaction (see scheme).

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