Advertisement

“Bottom-Up” Embedding of the Jørgensen–Hayashi Catalyst into a Chiral Porous Polymer for Highly Efficient Heterogeneous Asymmetric Organocatalysis

Authors

  • Chang An Wang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Zhi Kun Zhang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Tao Yue,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Ya Lei Sun,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Lei Wang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Wei David Wang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Dr. Yuan Zhang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Chong Liu,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author
  • Prof. Dr. Wei Wang

    Corresponding author
    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    • State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000 (P.R. China), Fax: (+86) 931-891-5557
    Search for more papers by this author

Abstract

original image

The only way is up! “Bottom-up” construction of a robust chiral porous polymer (JH-CPP) embedded with the Jørgensen–Hayashi catalyst (JH) has been successfully achieved for highly efficient heterogeneous organocatalysis. The high BET surface area, wide openings and interconnected nanopores of JH-CPP increase the accessibility of catalytic sites and as such the catalyst shows excellent activity in catalyzing the asymmetric Michael addition reaction (see scheme).

Ancillary