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Tuning the Electronic and Spin Complexity in Organic–Inorganic Molecular Hybrid Compounds

Authors

  • Dr. Jabor Rabeah,

    Corresponding author
    1. Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
    • Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
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  • Prof. Dr. Reinhard Stößer,

    1. Humboldt-University of Berlin, Institute of Chemistry, Brook-Taylor-Strasse 2, 12489 Berlin (Germany)
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  • Dr. Haijun Jiao,

    1. Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
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  • Prof. Dr. Sergey I. Troyanov,

    1. Humboldt-University of Berlin, Institute of Chemistry, Brook-Taylor-Strasse 2, 12489 Berlin (Germany)
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  • Dr. Jörg Radnik,

    1. Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
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  • Dr. Helmut Dwelk,

    1. Humboldt University of Berlin, Institute of Physics, Newton-Strasse 15, 12489 Berlin (Germany)
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  • Prof. Dr. Manfred Meisel,

    1. Humboldt-University of Berlin, Institute of Chemistry, Brook-Taylor-Strasse 2, 12489 Berlin (Germany)
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  • Prof. Dr. Angelika Brückner

    Corresponding author
    1. Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
    • Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51244
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Abstract

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Caught by the cage: New vanadium phosphonate cages with a fluoride template inside and charge-compensating transition-metal cations outside were prepared in a simple way. The charge and ligand sphere of the cation govern its interaction with the cage and can be used to modify the magnetic and redox properties of the cage, which also depend on the anionic template (see figure).

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