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Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers

Authors

  • Dr. Olivier Roubeau

    Corresponding author
    1. Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, Plaza San Francisco 50009 Zaragoza (Spain), Fax: (+34) 976761229
    • Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, Plaza San Francisco 50009 Zaragoza (Spain), Fax: (+34) 976761229
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Abstract

One-dimensional coordination FeII polymers constructed through triple N1,N2-1,2,4-triazole bridges form a unique class of spin-crossover materials, the synthetic versatility of which allows tuning the spin-crossover properties, the design of gels, films, liquid crystals, and nanoparticles and single-particle addressing. This Minireview provides the first complete overview of these very attractive switchable materials and their most recent developments.

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