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Intrinsically Sulfur- and Nitrogen-Co-doped Carbons from Thiazolium Salts

  1. Dr. Jens Peter Paraknowitsch1,*,
  2. Björn Wienert1,
  3. Dr. Yuanjian Zhang2,
  4. Prof. Arne Thomas1

Article first published online: 10 OCT 2012

DOI: 10.1002/chem.201202445

Issue

Chemistry - A European Journal

Chemistry - A European Journal

Volume 18, Issue 48, pages 15416–15423, November 26, 2012

Additional Information

How to Cite

Paraknowitsch, J. P., Wienert, B., Zhang, Y. and Thomas, A. (2012), Intrinsically Sulfur- and Nitrogen-Co-doped Carbons from Thiazolium Salts. Chem. Eur. J., 18: 15416–15423. doi: 10.1002/chem.201202445

Author Information

  1. 1

    Berlin Technical University, Institute of Chemistry, Division of Functional Materials, Hardenbergstrasse 40, 10623 Berlin (Germany)

  2. 2

    Southeast University, School of Chemistry and Chemical Engineering, Nanjing 211189 (P.R. China)

*Berlin Technical University, Institute of Chemistry, Division of Functional Materials, Hardenbergstrasse 40, 10623 Berlin (Germany)

Publication History

  1. Issue published online: 19 NOV 2012
  2. Article first published online: 10 OCT 2012
  3. Manuscript Received: 9 JUL 2012

Funded by

  • DFG

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Keywords:

  • carbon;
  • doping;
  • graphite;
  • nitrogen;
  • sulfur

Abstract

Carbon materials that are intrinsically co-doped with nitrogen and sulfur heteroatoms are synthesised by facile annealing of nitrile-functionalised thiazolium salts. Extremely high degrees of doping are achieved, especially for sulfur. The method further allows for direct tuning of the amounts of both N and S, establishing a new synthetic pathway in the emerging field of S-doped carbon materials.

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